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A piston and a piston rod are fitted inside a cylinder of length 0.508m and area 6.45 x 10^-3 m^2. Although the piston is quite thin, it weighs 9.07kg; the piston rod is 1.29 x 10 ^-3m^2 in area and weighs 4.53 kg. On top of the rod, but outside the cylinder, an 18.14kg weight is placed. Originally, gas in the cylinder above the piston is at atmospheric pressure while the piston is positioned in the middle of the cylinder. Gases in the cylinder both above and below the piston are helium and under these conditions may be considered ideal with a constant Cv = 12.6 J/mol K. The initial temperature everywhere is 311K. Assuming the cylinder, piston, and piston rod to be nonconducting and having a negligible heat capacity, discuss any heat or work interactions if the weight on top should fall off. What is the final state of the system when the piston has stopped and there is a balance of forces across the piston? Do not neglect the fact that during motion there may be some friction between moving parts. Consider cases in which the piston is (a) diathermal and (b) adiabatic.
At 25 degrees Celsius, the reaction: H3O+ + NH3 --> NH+ + OH- is first order in each reactant, and has a rate constant of 4.3x 10^10 M^-1 s^-1
A 500 ml volume of helium gas is at a pressure of 750 mm Hg and has a temperature of 30 degrees celcius. What is the volume of the same gas at STP?
Starting with Benzyl alcohol (PhCH2OH), 1-Proponal and any other organic or inorganic reagents outline a synthesis of 2-methyl-3-phenyl-2propen
A bottle contains 175 m: of insulin at a concentration of 20.0 mg/ml . What is the total mass of insulin in the bottle?
a sample of gas is collected over water at a temperature of 35.0C when the barometer pressure reading is 742.) torr. What is the partial pressure of oxygen?
a 10.00-mL sample of sulfuric acid from an automobile battery requires 35.08 mL of 2.12 M sodium hydroxide solution for complete neutralization. what is the molarity of the sulfuric acid? sulfuric acid contains two acidic hydrogens.
10 g of methane (CH4) is combusted in a calorimeter that has an empty heat capacity of 18 J/°C. The calorimeter contained 150 g of water.
Hemoglobin is the protein that transports O2through the blood from the lungs to the rest of the body. In doing so, each molecule of hemoglobin combines with four molecules
In a gas mixture, the partial pressures are nitrogen 420 torr , oxygen 125 torr , and helium 245 torr. What is the total pressure (torr) exerted by the gas mixture?
If the atmospheric pressure at 30 km is 28.0 torr and the temp is -48 C, what is the volume of the balloon when it bursts?
Write the Net Ionic Equation and determine the standard potential for the reaction between permanganate and tin(II). From the potential
A 10.0 balloon contains gas at a pressure of 640 torr. What is the new pressure of the gas at the 22.0 liters volumes if there is no change in temperature.
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