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A) for the electrophilic addition of HCL to 2-methyl-2-pentene use curved arrow notation to show the formation of the markovniknov & anti-markovnikov product. Label the types of carbocation formed as intermediates in each reaction pathway & show the structures of both the transition states for each reaction pathway (must show bonds being broken and/or made in transition state structure, must resemble species closest in energy per Hammond postulate)
B) Draw one energy diagram showing both reaction pathways & label all transition states, intermediates and products as well as activation energies. you may assume that the overall reactions are both exergonic while the first step in each reaction is endergonic.
C) Which product (markovniknov or anti-markovnikov) will be major product? why?
A piston has an external pressure of 8.00 torr How much work has been done if the cylinder goes from a volume of 0.130 liters to 0.450 liters.
A 0.0560 g quantity of acetic acid is dissolved in enough water to make 50.0 mL of solution. Calculate the concentration of H+, CH3COO-, and CH3COOH at equilibrium. Ka for acetic acid= 1.8x10^-5.
Why is molarity not the best means of stating acid strength? Is molarity the most representative form of quantifying acids and bases?
Important information about Degree of Unsaturation, Dieldrin, C12H8Cl6O, is a pentacyclic compound formerly used as an insecticide.
What would be the value of the change in concentration of C10H12/change in time during the same period of time? Explain why a catalyst for a forward reaction must also be a catalyst for the reverse reaction. Include an energy level diagram
A gas mixture composed of helium and argon has a density of 0.719g/l at a 743mmHg and 298k . What is composition of mixture by volume?
Describe at least four methods that could be used to attempt to separate the oil and water at home. Based on the four methods postulate which method would work better than the others.
how much heat (in KJ) is required to warm 10g of ice, initially at -10 degree celsius, to steam 110 degree celsius?
The rate constant (k) for a reaction was measured as a function of temperature. A plot of ln k versus 1/t (in K ) is linear and has a slope of ?1.13×10^4 K.
the rate of the constants for the above gas pharse reaction is 1.438M^-2 s^-1 at exactly 642.5 Kelvin and 21.64 M^-1 s^-1 at exactly 838.1 Kelvin. What is the value of the activation energy of the reaction in KJ/mole?
The equilibrium concentration of I2 is 0.05M. What is the equilibrium constant Kc for the reaction at this temperture? Express answer in K
Find the mass of the substance and the volume of a gas in a reaction - determine the mass of solid ammonium nitrate that must be used to obtain 0.145 L of dinitrogen oxide gas at STP.
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