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Question 1
With regard to the asymmetric Heck reaction - from the rccent literature (2010-2014) please give three examples that use the intermolecular and three examples that employ the intramolecular asymmetric Heck reactions as key steps in total synthesis or as steps studied for asymmetric methodology development.
In your analysis of these publications outline the chiral ligands used and draw a catalytic cycle for one initermolecular and one intramolecular reaction.
Question 2:
With regard to the asymmetric palladium - catalysed allylic substitution reaction - from the recent literature (2010-2014) please give five examples that use this transformation as ahoy step in total synthesis. In your analysis of these publications outline the chiral ligands used and draw a catalytic cycle for one of the examples you have chosen.
Evaluate particle diameter at different terminal gas velocities
Use Laplace transformation to solve the initial value problem
Describe the main purpose of the Globally Harmonised System of Classification and Labelling of Chemicals - Outline the bridging principles for classification of mixtures
Why fluids are important in chemical engineering - enormous number of materials normally exist as gases or liquids, or can be transformed into such phase and explain systematic description of change in fluid systems, mechanical change
What is the drawdown at the perimeter of the well pumping 225 gpm when both wells are operating?
The atmospheric pressure of 100k Pa acts on the other side of the piston. The gas is heated until the volume is doubled and the final pressure is 500 kPa. Calculate the work done by the gas.
Chemical Oxygen Demand (COD, microbiological quality of drinking waters, Oxygen Sag curves, landfill gas, integrated hazardous waste management plan
The effect of a hazardous substance depends on the concentration of the substance that is present in the body's systems. The concentration depends on the stages of toxicokinetics What are the four main stages of toxicokinetics
Why a substance is being heated at a fast rate the temperature of decomposition
(a) Describe the provisions of Occupational Safety and Health Act 2005 with regard to ‘Substances hazardous to health' (b) Describe four types of hazard which arise from the use of chemicals
Draw T-S diagram of the cycle.
Calculate the molar fraction of the system in the vapor phase
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