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(a) Draw the ?-only molecular orbital diagram for ML6 using AOM. Now, show what happens to the orbitals of the MO diagram after the Jahn-Teller tetragonal distortion is added for a d4 high spin complex. (Hint: The Jahn-Teller effect removes degeneracies in the MO diagram. Which MOs are affected?)
(b) Next consider a ?-donor ligand complex such as MX6n+ (x=halide) and its AOM diagram. Again the MO's are affected by a tetragonal distortion, changing both the molecular orbitals identified in the ?-only diagram as well as the molecular orbitals with ? symmetry. Sketch an example of one of these ? interactions which demonstrates why ? symmetry orbitals are also affected by the distortion.
Calculate the density of a block.
The Temperature is a constant 400.0 K. Calculate won, the work done on the system, and report the answer in Joules.
The solubility product of PbBr2 is 8.9 X 10^(-6). Determine the molar solubility in the pure water.
What was the Ka value calculated by the student if the pH of the solution was 2.60? Express your answer numerically using two significant figures
Estimate Delta G or this reaction at each of the following temperatures. (Assume that Delta H and Delta S do not change too much within the given temperature range.)
what starting material are needed to prepare the following compound using malonic ester synthesis
You have a sample of bone collected from Nevada and you find that it contains strontium-90 and exhibits an activity of 2.5 Bq. How much strontium-90 was present in the bone when the animal died 45 years ago?(The half-life of 90Sr is 29 years.)
Calculate the binding energy per nucleon (in MeV) for P-32 (atomic mass = 31.9739 u). mass H = 1.007825 u and mass n = 1.008665 u.
Mixture of equal amounts of both enantiomers of given compounds does not rotate the plane of polarized light. (e) Racemic mixture has the same melting point as both corresponding enantiomer.
What is the concentration of the vitamin C standard solution? Using a balance, 125mg of Vitamin C was weighed out and was added to a 100-mL beaker and dissolved in 50mL of DI water.
Why adding distioled water to the vinegar sample prior to beginning the titration does not affect the result of your determination of the molarity
Calculate the mass, in grams for a gold sample that absorbs 225 J to change its temperature from 15 Celsius to 47 degrees celsius.
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