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Suppose life has been discovered on another planet in a distant solar system. Organelles corresponding to our mitochondria transform energy by a Mitchell-like chemiosmotic mechanism. The flow of electrons drives the production of a pH gradient in the same direction. The only difference is the H+-ATP stoichiometry. •• Given that the pH on the outside of the xeno-mitochondrial membrane is 6.014, the pH on the inside is 7.568, ?G for ATP synthesis is 12.85 kcal/mol, and the alien body temperature is 27.3oC, calculate how many protons are required to pass through the xeno-FoF1-ATP synthase complex to synthesize one ATP. Round off your answer to the nearest integral value. (Assume, as we have done in class, that sufficient "power" to synthesize ATP exists when ?G for transporting protons across the membrane equals ?G for ATP synthesis.)
What is the percent by mass of NaHCO3 in a solution containing 50 g of NaHCO3 dissolved in 400 mL of H2O?
Compute the solubility of CO 2 in H 2 O at 25 oC in moles/L if the partial pressure of CO 2 in the headspace water sample is 1.56 atm.
Calculate the pH of the solution after the addition of 0.100 mL NaOH. The Ka for HC2H3O2 is 1.8x10^-5.
Calculate the work of expansion of the gas in joules (1 J = 9.87 10-3 atm·L). Assume all the energy is used to do work.
What volume of gas, measured at 690 torr and 40 degrees celcius, is required to form 29g of NaCl?
How many grams of water can be cooled from 45c to 15c by the evaporation of 65g of water? (The heat of vaporization of water in this temperature range is 2.4kj/g. The specific heat of water is 4.18j/k*mol .)
Methane reacts with oxygen to form carbon dioxide and water as shown:. determine how much methane must have reacted If 72 grams of water is formed,?
Calculate the molar mass of a gas that has a density of 0.232 g/L at 156 oC and 222 torr. Use R = 0.0821 L-atm/mol-K for the value of the gas constant.
Compute ΔU for the transformation; a = 0.136 m6Pa mol-2 ; b = 0.0391 L/mol.
Calculate total and individual w, q, ΔU, ΔH, and ΔS of an Otto engine operating on stoichiometric ethanol - oxygen gas mixture, with cylinder volume of 1 l and compression ratio of 18:1.
What mass of CaCO3 will produce 8.0 L of CO2, measured at standard temperature and pressure conditions? Molar mass of CaCO3 = 100. g per mole.
A 1-L flask is filled with 1.10 g of argon at 25 C. A sample of ethane vapor is added to the same flask until the total pressure is 1.20 atm . What is the partial pressure of argon,PAr , in the flask?
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