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The denaturation of double stranded DNA to 2 single strands of DNA (dsDNA ? 2 ssDNA) is described by the following T dependence of the equilibrium constant Keq = [ssDNA]2/[dsDNA]. Calculate for the process ?G°, ?H°, ?S°, and DCp at 36.8oC (the ‘°' refers to the reference temperature of 36.8°C). Attach all work and a well labeled van't Hoff plot and explain any assumptions you make. Finally, calculate ?G at 298K. ?T(°C)? K (M)? ? 31.8? 5.56 x 104? ? 36.8? 1.39 x 105? ? 41.8? 4.33 x 105? ? 46.7? 1.44 x 106 Summary of Results: ??G° = ?H° = ?S° = DCp = ?G at 298K = 1
If 10.00 mL of 0.050 M KI solution is mixed with 40.0mL of other reagents what would be the the diluted concentration of KI
N2O2 draw valence bond drawings for the resonance forms-clearly labeling the sigma and pi bonds and hybrid orbitals.
Derive the general expression for the work per kilomole of a van der waals gas in expanding reversibly and at a constant temperature
discuss the various ways that the Fischer esterification reaction can be run to maximize conversion to ester.
Blending of two wines with different concentrations of acid, Two wines are available for blending: One tank of 1000 L has a Titratable Acidity of 9.0 g/L and another tank containing 2000 L has a Titratable Acidity of 0.6 g/L.
Two particles with charges q1 and q2 are separated by distance d. Rank these scenarios according to the magnitude of the electrostatic (coulombic) potential energy.
another part says spectra of caffeine, benzoic acid, and a mountain dew sample in 0.10 M HCl. On a graph it has the points 8.74 mg/L for benzoic acid, 1.5 dilution for mountain dew soda,
To characterize the elution properties of the solute in a way independent of the geometry of the chromatographic column, the retention constant R = Vo / Ve is used. R is equal to the fraction of solute in the void volume Vo and
what is the concentration of chromium ion present in a 0.07092 M solution of potassium hydroxide in contact with a large excess of a precipitate
Determine the molarity of a solution of twenty grams of Ammonium bromide, NH4Br, in enough water to produce 132 mL of solution?
Which of the following substances form molecular crystals in solid form?
At a total air pressure of 2.78 and a temperature of 25.0 , what is the solubility of in a diver's blood? [Use the value of the Henry's law constant calculated in Part A]
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